Use s, 's, or s' depending on how the form is being used.
Example: Recordable DVDs are now more widely available.
DVDs is the plural form of DVD, so the writer has correctly added just an s, with no apostrophe.
Example: A recordable DVD's compatibility with different types of players may vary.
DVD's is the singular possessive form of DVD, so the writer has correctly added 's.
In the following example, the abbreviation is being used as a plural possessive, so s' needs to be added.
Example: Most DVDs' recording times are between four and six hours.